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sodium borohydride hazards

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( Sodium tetrahydroborate; SBH; reducing agent for the conversion of alde\ hydes and ketones to alcohols. 600.467 372.21 l EMC ( None of the chemicals in this product have a TPQ. /TT1 1 Tf 0.313 0.313 0.313 rg 602.774 533.597 l 600.467 166.092 l 0 -1.1 TD endstream endobj 28 0 obj<>stream Users should make their own investigations to determine th\ e suitability of the information for their particular pu)Tj 0 -1.201 TD (Eyes:)Tj EMC 10.764 341.46 l (Clean Air Act:)Tj f 0.457 0.449 0.431 rg /TT1 1 Tf 306 101.969 m 122.666 505.918 l ( R 34 Causes burns. ( )Tj 122.666 519.373 m f 122.666 492.463 l 120.755 455.71 l 0000002145 00000 n f 601.236 388.052 l 10.764 530.582 m Q h 600.467 678.415 l f MDL number MFCD00003518. H�tT�r�0��W�*R+# t�%w~ 1r��#���H�Q�\�Xh�zzz�B2�L�����jH���'����� P]�ju�:���G*el�џ�xJ�LvXfc��{�rV�����]l0��+GC� ���N�4�y�.h��ѓ��w��J������Cc{;$zҭE��~=CF~��W�V`��}{�fs6�q�� 600.467 763.915 l f 7.688 336.143 m 7.688 431.1 l 0.949 0.945 0.935 rg 602.774 386.514 l Keep away from acids. 120.755 443.793 l h 602.774 308.465 l (Equipment section. EMC 0 Tc 0 Tw 0 Ts 100 Tz 0 Tr 6.9196 0 0 6.9196 18 781.7488 Tm f (Section 3 - Hazards Identification )Tj 13.4548 0 0 13.4548 155.1384 684.7591 Tm 0000113518 00000 n f f EMC 485.294 430.338 l h /TT0 1 Tf EMC /TT0 1 Tf h (consult state and local hazardous waste regulations to ensure complete a\ nd accurate classification. 378.179 442.255 l 121.897 493.232 l )Tj /Artifact <>BDC f /TT0 1 Tf 7.688 533.657 m 602.774 673.569 l Q f Sodium borohydride is soluble in protic solvents such as water and lower alcohols. h h f -46.014 -1.555 Td 604.312 397.582 m 9.226 740.08 593.548 26.231 re W* n 0.949 0.945 0.935 rg /TT0 1 Tf ( )Tj 0 18 612 756 re f 7.688 680.662 l 484.526 443.024 m 604.312 680.662 l ( None of the chemicals in this product are listed as Toxic Pollutant\ s under the CWA. h 120.755 430.338 l /Artifact <>BDC /TT0 1 Tf 0 18 612 756 re 10.764 341.46 m ( S 28A After contact with skin, wash immediately with plenty of wate\ r )Tj 362.335 520.142 l h Section 3: Hazards Identification Potential Acute Health Effects: Extremely hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation. 306 115.424 l endstream endobj 85 0 obj<>stream 0 -1.201 TD endstream endobj xref /Artifact <>BDC h 0000112821 00000 n EMC : AC429130000; AC429131000 Synonyms SBH; Sodium tetrahydroborate Recommended Use Laboratory chemicals. (US FEDERAL)Tj Q 0.949 0.945 0.935 rg 600.467 332.299 l (Section 2 - Composition, Information on Ingredients )Tj T* f ( None listed. 9.226 458.778 l f 604.312 87.746 l 362.335 479.778 l 0 -1.199 TD f h 0 -1.201 TD 454.771 101.969 l Powerful reducing agent. 602.774 308.465 l 602.774 102.738 l 24.572 -0.001 Td Sodium borohydride. 19.692 0 Td 900-1011 (granular); 900-1015 (powder) NaBH 4) 16940-66-2. f 11.533 675.876 l 0 0 0 rg (European Labeling in Accordance with EC Directives)Tj 602.774 740.08 l Harmful if swallowed, inhaled, or absorbed through the skin. h 483.757 455.71 l 122.666 492.463 m h 0 18 612 756 re 363.104 532.828 m 11.533 209.97 l Q (rposes. 121.897 506.687 l /TT0 1 Tf (STATE)Tj 0 -1.201 TD (NIOSH/MSHA or European Standard EN 149 approved respirator if exposure l\ imits are exceeded or if irritation or )Tj Complete decomposition of a methanol solution requires nearly 90 min at 20 °C. f 602.774 386.514 l 602.774 334.605 l 601.236 677.646 l ( If swallowed, do NOT induce vomiting. EMC h Q 604.312 87.746 l 600.467 438.26 l f 0 -1.201 TD ( water and seek medical advice. 9.226 491.695 l /WebCaptureFN <>BDC ( )Tj 9.226 520.142 l h h 0.801 0.801 0.801 rg Sodium borohydride is an odorless white to gray-white microcrystalline powder that often forms lumps. (Section 9 - Physical and Chemical Properties )Tj f h 0000001568 00000 n f 9.226 142.258 l h 454.771 101.969 l 0.753 0.753 0.753 rg /TT0 1 Tf 10.764 764.683 m 600.467 363.757 l (OSHA Vacated PELs:)Tj 7.688 306.927 l 484.526 443.024 m W* n 0 -1.1 TD 603.543 505.918 l 602.774 559.353 l 602.774 533.597 l EMC )Tj 0 -1.201 TD 0 -1.201 TD W* n Store in a cool, dry, well-\ ventilated area away from )Tj f 0000059731 00000 n 0.801 0.801 0.801 rg 10.764 388.052 l 0 18 612 756 re Q 0000000000 00001 f 600.467 706.034 l 9.226 186.136 l )Tj 603.543 492.463 m /TT1 1 Tf f W* n h 0 -1.2 TD f h q Provide ventilation. 602.774 101.2 l )Tj 602.774 494.862 l 600.467 471.028 l Q US EPA )Tj 376.641 430.338 l (Ingestion:)Tj 0000002709 00000 n 9.226 676.109 l h h 0 -1.2 TD f /Artifact <>BDC 601.236 394.506 l 603.543 479.009 l h h (Section 313)Tj q h 363.104 519.373 l )Tj 10.764 677.646 m /Artifact <>BDC 0.313 0.313 0.313 rg 11.533 583.187 l /TT1 1 Tf 0 18 612 756 re 10.7638 0 0 10.7638 7.6884 376.0584 Tm startxref 9.9358 0 0 9.9358 7.6884 718.5535 Tm 8.6495 0 0 8.6495 45.3171 105.8613 Tm /TT0 1 Tf 156.46 102.738 l Health & Safety Reporting List None of the chemicals are on the Health & Safety Reporting List. 602.774 505.149 l 0 0 0 rg 0 -1.201 TD 363.873 493.232 l 0 -1.201 TD 7.688 367.601 m f f 377.41 429.569 l EMC /TT0 1 Tf 0 -1.101 TD T* ( )Tj 600.467 388.82 l 601.236 310.002 l 9.226 101.2 l h Do not allow contact with water. /T1_0 1 Tf Hydride ions are capable of attacking the carbonyl carbon by transferring with their bonding electron pair to generate an alkoxide ion. 9.9358 0 0 9.9358 7.6884 656.8288 Tm 122.666 492.463 m The heat of this reaction may be sufficient to ignite the hydrogen. 0 0 0 rg 122.292 430.338 l 602.774 673.569 l 0 0 0 rg 122.666 532.828 l f f h BT (TSCA Significant New Use Rule)Tj 363.873 532.059 l 376.641 455.71 l h 0.753 0.753 0.753 rg ( )Tj h -33.167 -2.577 Td 602.774 442.255 l 157.997 89.283 l 122.666 505.918 m 604.312 140.72 l W* n 8.457 505.918 m uuid:b3c23da2-03b5-40e1-9af7-8e64e5dfac03 ( As in any fire, wear a self-contained breathing apparatus in pressure-d\ emand, MSHA/NIOSH )Tj EMC /TT0 1 Tf )Tj f Q 601.236 470.259 l (wet or moist. 11.533 332.299 l /T1_0 1 Tf (Specific Gravity/Density:)Tj 603.543 532.828 l 121.897 506.687 l 11.533 675.876 l /T1_0 1 Tf W* n 484.526 443.024 m ( not available. 0 -1.201 TD 0000059326 00000 n h ( Treat symptomatically and supportively. 10.764 714.383 m 602.774 369.903 l f 0 -1.201 TD ( CAS # 16940-66-2: immediate, fire, reactive. /Artifact <>BDC (Flash Point:)Tj 0 -1.201 TD 376.641 442.255 l 0 -1.1 TD 376.641 442.255 l 0000059562 00000 n )Tj 377.41 443.024 m f 0 -1.201 TD Sodium Borohydride Applications - Has many uses including the following : - for the manufacture of Sodium Dithionite as a bleaching agent. q /TT1 1 Tf 601.236 411.117 m Q 455.54 102.738 147.234 11.917 re q 602.774 334.605 l 0000030840 00000 n 121.897 479.778 l 11.533 363.757 l 9.226 673.569 l 10.764 434.175 l /TT0 1 Tf 363.873 533.597 l q 9.9358 0 0 9.9358 212.3056 726.722 Tm W* n 7.688 384.976 l f T* f 603.543 456.479 m f 10.764 741.618 l /TT0 1 Tf 7.688 467.183 l 123.434 493.232 l f 0 -1.201 TD /WebCaptureBG BMC /TT0 1 Tf ET f ( incidental, )Tj 157.229 115.424 m EMC 600.467 684.507 l /TT1 1 Tf Sodium borohydride 16940-66-2 100 Toxicological Data on Ingredients: Sodium borohydride: ORAL (LD50): Acute: 160 mg/kg [Rat]. /TT0 1 Tf (H4BNa )Tj 13.8392 0 0 13.8392 212.2048 754.9995 Tm NaBH 4 + 3 HO 2 CCH 3 → NaBH(O 2 CCH 3) 3 + 3 H 2 f f /TT0 1 Tf ( )Tj 604.312 213.814 l Q 0 -1.1 TD EMC 120.755 430.338 l 7.688 368.366 l 600.467 529.813 l Uses advised against Food, drug, pesticide or biocidal product use. h uuid:04acfd23-d467-49f5-b08f-8c5b972f0bc7 602.774 520.142 l 8.457 519.373 m f )Tj 9.995 0 0 9.995 432.3956 748.688 Tm (Clean Water Act:)Tj x�b```f``K``e`�y�A��X��,/ �������]�)�8g���@����� 7.688 703.787 m 602.774 432.638 l 485.294 443.793 l 91, p. 259-264. 9.226 676.109 l 11.533 166.092 l 0.313 0.313 0.313 rg -50.921 -1.555 Td 11.5327 0 0 11.5327 247.3103 740.5341 Tm 602.774 412.655 l (WGK \(Water Danger/Protection\))Tj 601.236 530.582 l h 0 0 0 rg 8.457 479.009 l 601.236 741.618 l q (Personal Protective Equipment)Tj BT 9.226 505.149 l 9.226 114.655 l 122.666 479.009 l BT 7.688 457.248 m 0 18 612 756 re q 362.335 532.059 l /TT0 1 Tf h 9.226 386.514 l &��9����頃�����!��UJc��n2�����`! 377.41 443.024 l 0.753 0.753 0.753 rg 603.543 429.569 l 0.753 0.753 0.753 rg 363.104 492.463 m 7.688 431.1 m 0 0 0 rg 7.688 496.4 m f 602.774 532.059 l f 602.774 715.921 l 0 18 612 756 re 0 -1.2 TD /Artifact <>BDC f (Synonyms:)Tj ( )Tj endstream endobj 34 0 obj(https://fscimage.fishersci.com/msds/95397.htm) endobj 35 0 obj<> endobj 36 0 obj<> endobj 37 0 obj<> endobj 38 0 obj<> endobj 39 0 obj[36 0 R] endobj 40 0 obj(https://fscimage.fishersci.com/msds/95397.htm) endobj 41 0 obj(vp~¿’wˆŸm Cû�Ô{) endobj 42 0 obj<> endobj 43 0 obj<> endobj 44 0 obj(çÔõë‰5Eqö£¸. 363.104 505.918 m ( )Tj EMC 0 -1.1 TD 122.292 443.793 l Higher exposures can cause a build-up of fluid in the lungs (pulmonary edema), a medical emergency, with severe shortness of breath. (adequate ventilation. 0000007443 00000 n 0 51 363.873 533.597 l (No information available.

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November 13, 2020 |

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